Lucas era Star Wars makeup tends to follow the trends of the time the movie was made as well as take the approach of a more neutral and subdued color palette. This look, like many that Padmè wears in [Attack of the Clones,] has a very natural look, with little to no color outside of the lipsticks.
(Note: This is the approximation from analogizing the photos of Padmè makeup, all of these suggestions should be plaid around with to fit each Padmè perfectly.)
Natural looking foundation, any foundation with a setting powder should work well, plus some concealer to give a finished look. It is very natural looking which is the key to most Star Wars makeup, (Padmè does not have any contouring in this look.) For the purposes of movie magic there are likely high-lights and low-lights that are not important to cover here.
As far as eye-shadow goes Padmè wears a warm light taupe brown only on the back of her upper eyelid.
There is a very light ashy taupe color, this color is only applied to the back of the lid; there is no color on the crease and brow bone, [no smoky eye]. (Note: occasionally the taupe color appears to be blended and winged out a very little past the outer corner of the eye. It is possible that there is a second lighter sandy-brown color that is almost undetectable on the eyelids outer corner and into the crease.)
It does not appear that Padmè wears any eyeliner on her lower lid or water line, she may be wearing either a black or brown eyeliner on her upper lid just above her lash line, but it is almost undetectable and covered mostly by the mascara. You may consider skipping eyeliner and just go heavy on the mascara near the base of the lashes. She also appears to be wearing mascara, [but noticeably false lashes do not appear to have been used].
Padmè’s wears a pinky nude blush, and the application is very light and almost hard to see. The blush is applied to the apples of the cheeks and along in a narrow oval up to the cheek bone.
Padmè wears a pinkish light raspberry color in a semi gloss lipstick is applied to Padmè’s natural lip shape.
Images from Cap-that.com